From Skype: http://www.skype.com/intl/en-us/support/user-guides/call-with-video/
Make sure you’ve got a webcam and check:
– it’s plugged into your computer
– you’ve installed the software that came with it
– it’s switched on.
In your Contact list, find the person you want to talk to.
Click on them.
In the main window, click the green Video call button.
Smile, wave, say hello!
In the same way, You can Record Skype video calls with SuperTinTin.